4.8 Article

Thermoinduced structural-transformation and thermochromic luminescence in organic manganese chloride crystals

Journal

CHEMICAL SCIENCE
Volume 10, Issue 13, Pages 3836-3839

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8sc04711a

Keywords

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Funding

  1. National Science Fund for Distinguished Young Scholars [21825106]
  2. National Natural Science Foundation of China [21671175]
  3. Program for Science & Technology Innovation Talents in Universities of Henan Province [164100510005]
  4. Program for Innovative Research Team (in Science and Technology) in Universities of Henan Province [19IRTSTHN022]
  5. Zhengzhou University

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The [Mn2Cl9](5-) mode of red emissive (C4NOH10)(5)Mn2Cl9 center dot C2H5OH under thermal treatment will be cleaved into [MnCl4](2-) in the green emissive (C4NOH10)(2)MnCl4 with the departure of ethanol. The rapid conversion of luminescence from red to green provides new insight into the luminescence origin and thermal stability of organic-inorganic metal halide hybrids.

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