A self-healing flexible transparent conductor made of copper nanowires and polyurethane

A self-healing flexible transparent conductor comprising a core-shell copper nanowire network and healable polyurethane sheath was developed. The polyurethane pre-polymer containing furan rings was cross-linked with N,N'-(4,4'-methylenediphenyl) dimaleimide via a Diels-Alder reaction to form the healable network polymer. This thin polymer layer solders the copper nanowires and confines the nanowire network on the substrate surface. The nanocomposite conductor exhibits a sheet resistance of 22.3 Omega sq(-1) with 66.5% transmittance at 550 nm. 98% of the surface conductivity can be recovered in 3 min at 120 degrees C, and the damaging-healing behavior could be repeated 5 times at the same position. The present work provides a simple way to fabricate advanced flexible transparent conductors. (C) 2017 Elsevier Ltd. All rights reserved.