Journal
POLYMER CHEMISTRY
Volume 10, Issue 14, Pages 1823-1831Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8py01785a
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Funding
- Industrial Liaison Program in Polymerization in Dispersed Media (3 M)
- Industrial Liaison Program in Polymerization in Dispersed Media (Akzo Nobel)
- Industrial Liaison Program in Polymerization in Dispersed Media (Allnex)
- Industrial Liaison Program in Polymerization in Dispersed Media (Arkema)
- Industrial Liaison Program in Polymerization in Dispersed Media (Asian Paints)
- Industrial Liaison Program in Polymerization in Dispersed Media (BASF)
- Industrial Liaison Program in Polymerization in Dispersed Media (DSM)
- Industrial Liaison Program in Polymerization in Dispersed Media (Inovyn)
- Industrial Liaison Program in Polymerization in Dispersed Media (Stahl)
- Industrial Liaison Program in Polymerization in Dispersed Media (Solvay)
- Industrial Liaison Program in Polymerization in Dispersed Media (Synthomer)
- Industrial Liaison Program in Polymerization in Dispersed Media (Vinavil)
- Industrial Liaison Program in Polymerization in Dispersed Media (Wacker)
- Post-Doctoral fellowship Juan de la Cierva - Incorporacion, from the Ministry of Economy and Competitiveness of Spain [IJCI-2016-28442]
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Cellulose nanocrystals (CNCs) possess an incredible degree of mechanical strength which makes them interesting candidates in the design of composite materials. In this work, we demonstrate the synthesis of CNC armored latex particles by an emulsion polymerization process. A cationic initiator was used to ensure the adsorption of the negatively charged CNCs onto the latex particle surface. Through careful balance of the cationic/anionic species involved in the adsorption process it is demonstrated that it is possible to achieve stable latexes with high conversion and low particle size. Films were cast from the CNC armored latexes and atomic force microscopy was used to confirm the adsorption to the surface and their even distribution throughout the film. The mechanical properties of the films were measured demonstrating that the addition of CNCs led to a brittle film with extremely high Young's modulus. Blends of the CNC armored particles with a cationically stabilized latex were fabricated in order to demonstrate the potential to produce mechanically strong polymer films for use in conventional coatings applications.
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