4.6 Article

Bimetallic zeolitic imidazolate frameworks for symmetric electrical double-layer supercapacitors with aqueous electrolytes

Journal

MATERIALS LETTERS
Volume 207, Issue -, Pages 129-132

Publisher

ELSEVIER
DOI: 10.1016/j.matlet.2017.07.055

Keywords

Aqueous electrolyte; Electrical double-layer supercapacitor; Zeolitic imidazolate framework

Funding

  1. Energy Efficiency and Resources Core Technology Program through the Korea Institute of Energy Technology Evaluation and Planning within the Ministry of Trade, Industry and Energy, Korea [20142020103790]
  2. Kangwon National University
  3. Korea Evaluation Institute of Industrial Technology (KEIT) [20142020103790] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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We have investigated a facile synthesis of nanoporous carbon using a bimetallic (Co2+ and Zn2+) zeolitic imidazolate framework (ZIF) as a precursor. The properties of the as-prepared bimetallic ZIF-derived carbon, including the specific surface area, porosity, and degree of graphitization, are precisely controlled. This material has been directly applied in a symmetric electrical double-layer supercapacitor (EDLC). The specific capacitance of the symmetric EDLC is estimated to be 10.5 F.g(-1) at a high current density of 10 A.g(-1) in 0.5 M sulfuric acid. (C) 2017 Elsevier B.V. All rights reserved.

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