Journal
JOULE
Volume 3, Issue 4, Pages 1140-1151Publisher
CELL PRESS
DOI: 10.1016/j.joule.2019.01.004
Keywords
-
Funding
- National Key Research & Development Projects of China [2017YFA0206600]
- National Natural Science Foundation of China [21875286, 21761132001, 91633301]
- Science Fund for Distinguished Young Scholars of Hunan Province [2017JJ1029]
- NSFC [91633301]
- CUHK direct grant
- NSFC/RGC Joint Research Scheme [N_CUHK418/17]
- NSERC
- CIFAR
- Sentinelle Nord
Ask authors/readers for more resources
Recently, non-fullerene n-type organic semiconductors have attracted significant attention as acceptors in organic photovoltaics (OPVs) due to their great potential to realize high-power conversion efficiencies. The rational design of the central fused ring unit of these acceptor molecules is crucial to maximize device performance. Here, we report a new class of non-fullerene acceptor, Y6, that employs a ladder-type electron-deficient-core-based central fused ring (dithienothiophen[3.2-b]-pyrrolobenzothiadiazole) with a benzothiadiazole (BT) core to fine-tune its absorption and electron affinity. OPVs made from Y6 in conventional and inverted architectures each exhibited a high efficiency of 15.7%, measured in two separate labs. Inverted device structures were certified at Enli Tech Laboratory demonstrated an efficiency of 14.9%. We further observed that the Y6-based devices maintain a high efficiency of 13.6% with an active layer thickness of 300 nm. The electron-deficient-core-based fused ring reported in this work opens a new door in the molecular design of high-performance acceptors for OPVs.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available