Journal
BATTERIES-BASEL
Volume 5, Issue 1, Pages -Publisher
MDPI
DOI: 10.3390/batteries5010036
Keywords
lithium-ion; NMC; aging; ampere-hour throughput; incremental capacity analysis
Funding
- EDF RD
- ANRT Agence Nationale de la Recherche et de la Technologie of France
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Reliable development of LIBs requires that they be correlated with accurate aging studies. The present project focuses on the implementation of a weighted ampere-hour throughput model, taking into account the operating parameters, and modulating the impact of an exchanged ampere-hour by the well-established three major stress factors: temperature, current intensity (rated), and state of charge (SoC). This model can drift with time due to repeated solicitation, so its parameters need to be updated by on-field measurements, in order to remain accurate. These on-field measurements are submitted to the so-called Incremental Capacity Analysis method (ICA), consisting in the analysis of dQ/dV as a function of V. It is a direct indicator of the state of health of the cell, as the experimental peaks are related to the active material chemical/structural evolution, such as phase transitions and recorded potential plateaus during charging/discharging. It is here applied to NMC/graphite based commercial cells. These peaks' evolution can be correlated with the here-defined Ah-kinetic and t-kinetic aging, which are chemistry-dependent, and therefore, has to be adjusted to the different types of cells.
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