Journal
ACS OMEGA
Volume 4, Issue 3, Pages 6035-6043Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsomega.9b00361
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Funding
- University Grants Commission (UGC), India under the National Fellowship for Higher Education (NFHE) Scheme
- SERB, DST [SB/EMEQ-006/2013]
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A novel approach has been developed for the synthesis of a wide range of alpha-ketoacetals by the reaction of alkyl/aryl methyl ketones and aliphatic alcohols in the presence of selenium dioxide catalyzed by p-toluenesufonic acid. This method represents a general route to obtain a wide variety of alpha-ketoacetals in a simple, rapid, and practical manner. This approach is particularly attractive because of the easy availability of the starting materials, mild reaction temperature, and good yields of the products. The resulting alpha-ketoacetals are of much synthetic value as organic intermediates.
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