Journal
NEW JOURNAL OF CHEMISTRY
Volume 43, Issue 13, Pages 5020-5031Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8nj05616a
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Funding
- UGC
- UGC-CAS II programme, Department of Chemistry, Jadavpur University
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An X-ray characterized tetranuclear nickel(II)/lead(II) complex has been synthesized and characterized by elemental analysis, IR and single crystal X-ray diffraction studies. Single crystal X-ray analysis confirms that the complex contains two [(NiO2)Pb] cores joined with two DMF molecules. The complex shows interesting electrical properties. The optical band gap energy of the synthesized ligand and the complex has been evaluated as 3.87 and 3.08 eV, respectively. The solid state UV measurement implies the semiconductor behavior of the complex. The complex based device has been determined experimentally to behave as a Schottky diode.
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