Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 25, Pages 3638-3641Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc00769e
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Funding
- National Natural Science Foundation of China [21822507, 21625403, 21761132020, 21574129]
- National Key Research and Development Program of China - MOST [2018YFE0100600]
- Strategic Priority Research Program of Chinese Academy of Sciences [XDB12010200]
- Youth Innovation Promotion Association of Chinese Academy of Sciences [2017265]
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In this manuscript, we report a disk-type polyarene consisting of an all-hexagon -framework and four BN units. It exhibits intriguing electronic structures and opto-electronic properties, such as locally modulated (anti)aromaticity, strong red fluorescence and n-type semiconductor characteristics, thus representing a new kind of pi-molecule containing B <- N units.
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