4.7 Article

A disk-type polyarene containing four B←N units

Journal

CHEMICAL COMMUNICATIONS
Volume 55, Issue 25, Pages 3638-3641

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc00769e

Keywords

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Funding

  1. National Natural Science Foundation of China [21822507, 21625403, 21761132020, 21574129]
  2. National Key Research and Development Program of China - MOST [2018YFE0100600]
  3. Strategic Priority Research Program of Chinese Academy of Sciences [XDB12010200]
  4. Youth Innovation Promotion Association of Chinese Academy of Sciences [2017265]

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In this manuscript, we report a disk-type polyarene consisting of an all-hexagon -framework and four BN units. It exhibits intriguing electronic structures and opto-electronic properties, such as locally modulated (anti)aromaticity, strong red fluorescence and n-type semiconductor characteristics, thus representing a new kind of pi-molecule containing B <- N units.

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