4.7 Article

High-Thermal-Transport-Channel Construction within Flexible Composites via the Welding of Boron Nitride Nanosheets

Journal

ACS APPLIED NANO MATERIALS
Volume 2, Issue 1, Pages 360-368

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsanm.8b01939

Keywords

boron nitride nanosheets; thermal conductivity; antistatic; composites; PDMS

Funding

  1. National Natural Science Foundation of China [51573201]
  2. NSFC-Zhejiang Joint Fund for the Integration of Industrialization and Informatization [U1709205]
  3. Public Welfare Project of Zhejiang Province [2016C31026]
  4. Scientific Instrument Developing Project of the Chinese Academy of Sciences [YZ201640]
  5. Project of the Chinese Academy of Sciences [KFZD-SW-409]
  6. Science and Technology Major Project of Ningbo [2016S1002, 2016B10038]

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Efficient heat dissipation is a prerequisite for further improving the integration of devices. However, the polymer composites are not satisfying heat dissipation. For that reason, high-thermal-transport channels were E manufactured by the direct freezing method and boron nitride nanosheets (BNNS) were further welded by carbonization. Composites with high thermal conductivity (7.46 W m(-1) K-1) were obtained by immersion in poly-(dimethylsiloxane) (PDMS). Thermal conductivity enhancement of composites reached about 3900% at 15.8 vol % loading of BNNS. Besides, the composites maintained the structural flexibility of PDMS and allowed repeated bending and twisting. In addition, the PDMS composites exhibited excellent antistatic properties because of a conductive network formed by residual carbon. Therefore, dust could be avoided and the surface kept clean. This provides a better choice for thermal management materials and meets the antistatic requirements of the devices.

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