Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 7, Issue 15, Pages 9051-9058Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ta02067e
Keywords
-
Funding
- National Natural Science Foundation of China [51871059, 51601040, 51571063]
- Science and Technology Commission of Shanghai Municipality [15YF1401300]
- National Key Research and Development Program of China [2017YFA0403703]
Ask authors/readers for more resources
The extended application of sodium ion batteries (SIBs) to cold climates or high-altitude areas has been severely impeded by the sluggish solid-diffusion process of Na+ in the anode material. Herein, we for the first time report CoGa2S4 as a novel anode material for SIBs, exhibiting superior full cell performance when coupled with a high-voltage Na-0.7[Mn0.6Ni0.2Mg0.2]O-2 (NMN-2) cathode in a voltage range of 1.0-4.1 V. More importantly, when tested at an ultra-low temperature of -60 degrees C, CoGa2S4 delivers a high reversible capacity close to 100 mA h g(-1) upon 1000 cycles at a current density of 1 A g(-1). This excellent low-temperature performance is attributed to the fact that after the first discharge process of the CoGa2S4 electrode, the Ga-based sulfide loses its electrochemical reaction activity, but fortunately it can serve as a high ionic conductivity medium, facilitating the conversion reaction of cobalt sulfides. The phenomenon that the Ga-based sulfide in CoGa2S4 sacrifices the capacity, but allows cobalt sulfides to withstand temperature variation sheds light on designing high performance sub-zero temperature anodes for SIBs.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available