Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 38, Issue 13, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.201700040
Keywords
atom transfer radical polymerization; intramolecular charge transfer; organocatalysis; photochemistry; photoredox catalysis
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Funding
- University of Colorado Boulder
- Advanced Research Projects Agency-Energy [DE-AR0000683]
- American Chemical Society Petroleum Research Fund [56501-DNI7]
- National Institute of General Medical Sciences of the National Institutes of Health [R35GM119702]
- National Science Foundation Graduate Research Fellowship
- U.S. Department of Education Graduate Assistance in Areas of National Need Program
- Marian Sharrah Fellowship from the CU Boulder Department of Chemistry and Biochemistry
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The recent development of organocatalyzed atom transfer radical polymerization (O-ATRP) represents a significant advancement in the field of controlled radical polymerizations. A number of classes of photoredox catalysts have been employed thus far in O-ATRP. Analysis of the proposed mechanism gives insight into the relevant photophysical and chemical properties that determine catalyst performance. Discussion of each of the classes of O-ATRP catalysts highlights their previous uses, their roles in the development of O-ATRP, and the distinctive properties that govern their polymerization behavior, leading to a set of design principles for O-ATRP catalysts. Remaining challenges for O-ATRP are presented, as well as prospects for further improvement in the application scope of O-ATRP.
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