Journal
CHEMPHOTOCHEM
Volume 3, Issue 4, Pages 193-197Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cptc.201900018
Keywords
iodoperfluoroalkylation; perylenediimides; photochemistry; radicals; synthetic methods
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Funding
- University of Trieste
- FSE-EUS/4 [FP1799043001]
- Spanish State Research Agency [MDM-2017-0720]
- INSTM
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We describe a novel efficient photochemical procedure for the direct iodoperfluoroalkylation of terminal olefins. The process uses a simple and inexpensive perylenediimide (PDI) in an extremely low catalytic loading and occurs with visible light irradiation. The reported methodology is highly viable from a synthetic point of view, since it proceeds under mild reaction conditions with a significant rate of production. Preliminary mechanistic investigations are also reported.
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