Journal
LUMINESCENCE
Volume 33, Issue 1, Pages 29-33Publisher
WILEY
DOI: 10.1002/bio.3368
Keywords
chemosensor; fluorescence; turn-on; zinc ion
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Funding
- National Natural Science Foundation of China [21371155, 21501150, 51502079]
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A series of naphthaldehyde-2-pyridinehydrazone derivatives were discovered to display interesting turn-on' fluorescence response to Zn2+ in 99% water/DMSO (v/v) at pH7.0. Mechanism study indicated that different substituent groups in the naphthaldehyde moiety exhibited significant influence on the detection of Zn2+. The electron rich group resulted in longer fluorescence wavelengths but smaller fluorescence enhancement for Zn2+. Among these compounds, 1 showed the highest fluorescence enhancement of 19-fold with the lowest detection limit of 0.17mol/L toward Zn2+. The corresponding linear range was at least from 0.6 to 6.0mol/L. Significantly, 1 showed an excellent selectivity toward Zn2+ over other metal ions including Cd2+.
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