Journal
NANOSCALE
Volume 11, Issue 12, Pages 5151-5157Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9nr01058k
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Funding
- National Natural Science Foundation of China [21671175, 21371153, 21371154, 21801228]
- Program for Science & Technology Innovation Talents in Universities of Henan Province [164100510005]
- Program for Innovative Research Team (in Science and Technology) in Universities of Henan Province [19IRTSTHN022]
- Zhengzhou University
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The synthesis of atom-precise analogues of homometallic nanoclusters remains a great challenge. Herein we report the first pair of atom-precise copper/silver-thiolate halide cluster analogues, namely [Cu-17/Ag17I3S(C2B10H10S2)(6)(CH3CN)(11)] (Cu-17 and Ag-17), obtained by bottom-up self-assembly and complete-metal-exchange-induced cluster-to-cluster transformation, respectively. The differences in optical absorption and emission of these analogues were fully elucidated by experimental and theoretical methods.
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