4.7 Article

Palladium NPs supported on sulfonic acid functionalized metal-organic frameworks as catalysts for biomass cascade reactions

Journal

DALTON TRANSACTIONS
Volume 48, Issue 17, Pages 5515-5519

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9dt00348g

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Funding

  1. National Key Research and Development Program of China [2017YFA0206500, 2017YFA0206801]
  2. National Basic Research Program of China [2015CB932301]
  3. National Natural Science Foundation of China [21671163, 21721001]
  4. Fundamental Research Funds for the Central Universities [20720160026]

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Highly distributed Pd NPs supported on the surface of sulfonic acid functionalized metal organic frameworks (MIL-101-SO3H) were synthesized via a simple thermal decomposition method. The as-synthesized Pd/MIL-101-SO3H was used to catalyze a hydrogenation/esterification cascade reaction for the conversion of biomass derivatives (furoic acid) into high value chemicals (ethyl tetrahydro-2-furoate).

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