Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 31, Pages 4538-4541Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc00581a
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Funding
- National Natural Science Foundation of China [21875146, 21501161]
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A novel compound with four mixed anions, Y8O(OH)(15)(CO3)(3)Cl, exhibiting an infrequent three-dimensional (3-D) inorganic cationic framework, has been successfully designed and synthesized by introducing -conjugated planar triangular CO3 groups and chloride anions into a rare earth oxide system, which exhibits good balance among its wide UV transmission range, large second harmonic generation (SHG) coefficient and suitable birefringence to meet the phase-matching condition, indicating that the titled compound is a promising short-wave UV nonlinear optical material.
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