Journal
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
Volume 75, Issue -, Pages 547-+Publisher
INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S2056989019004055
Keywords
crystal structure; copper complex; imidazolidine ligand
Categories
Funding
- Conselho Nacional de Desenvolvimento Cientifico e Tecnologico [141341/2013-0]
- Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior [001]
- Fundacao Carlos Chagas Filho de Amparo a Pesquisa do Estado do Rio de Janeiro [E-26/111.177/2011, E-26/110.157/2014]
Ask authors/readers for more resources
In the crystal structure of the title complex, [CuCl(C17H24N8)]ClO4, the copper(II) metal exhibits an N4Cl pentacoordinate environment in a distorted square-pyramidal geometry. Coordination to the metal centre occurs through the three 1-methylimidazole N atoms from the pendant groups, one amine N atom from the imidazolidine moiety and one chlorido anion. Intermolecular interactions take place at two of the 1-methyl-imidazole rings in the form of parallel-displaced pi-pi stacking interactions forming chains parallel to the a axis. Three O atoms of the perchlorate anion are rotationally disordered between two orientations with occupancies of 0.5.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available