4.6 Article

Highly Controlled Nanoporous Ag Electrode by Vaporization Control of 2-Ethoxyethanol for a Flexible Supercapacitor Application

Journal

LANGMUIR
Volume 33, Issue 8, Pages 1854-1860

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.langmuir.6b04625

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Funding

  1. National Research Foundation of Korea [901368]
  2. MSIP [NRF2016R1A5A1938472]
  3. Global Frontier R&D Program on Center for Multiscale Energy System [2012054172]
  4. Creative Materials Discovery Program-Ministry of Science, ICT Future [NRF2016M3D1A1900035]
  5. R&D Convergence Program

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Controlling the surface morphology of the electrode on the nanoscale has been studied extensively because the surface morphology of a material directly leads to the functionalization in various fields of studies. In this study, we designed a simple and cost-effective method to fine-tune the surface morphology and create controlled nanopores on the silver electrode by utilizing 2-ethoxyethanol and two successive heat treatments. High electrical conductivity and mechanical robustness of nanoporous silver corroborate its prospect to be employed in various applications requiring a certain degree of flexibility. As a proof-of-concept, a high-performance supercapacitor was fabricated by electrodepositing MnO2. This method is expected to be useful in various electronic applications as well as energy storage devices.

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