Journal
LANGMUIR
Volume 33, Issue 32, Pages 7881-7888Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.langmuir.7b01837
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Funding
- [RG86209]
- EPSRC [1799423] Funding Source: UKRI
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Neutron reflectometry has been used to study the adsorption of the anionic surfactant bis(2-ethylhexyl) sulfosuccinate cesium salt on the anionic surface of mica. Evidence of significant adsorption is reported. The adsorption is reversible and changes little with pH. This unexpected adsorption behavior of an anionic molecule on an anionic surface is discussed in terms of recent models for surfactant adsorption such as cation bridging, where adsorption has been reported with the divalent ion calcium but not previously observed with monovalent ions.
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