4.6 Article

Thiol-Stabilized Gold Nanoparticles: New Ways To Displace Thiol Layers Using Yttrium or Lanthanide Chlorides

Journal

LANGMUIR
Volume 33, Issue 43, Pages 12149-12154

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.langmuir.7b01898

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Funding

  1. Canada Research Chair Program (Tier I)
  2. Natural Sciences and Engineering Research Council of Canada (Discovery program)
  3. Canada Foundation for Innovation

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We use the aurophilic interactions shown by lanthanides to overcome the sulfur gold interaction. UV vis and X-ray photoelectron spectroscopy confirm that yttrium or lanthanide chlorides easily displace sulfur ligands from the surface of thiol-stabilized gold nanoparticles.

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