Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 6, Issue 10, Pages 1649-1654Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9qo00240e
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Funding
- National Natural Science Foundation of China [NSFC 21472073, 21532001, 21772075]
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Herein, a novel photo-induced amine-free radical reductive dehalogenation of inactivated aryl/ alkyl bromides and chlorides with a palladium complex is described, which reveals excellent functional group compatibility and broad substrate scope. Extensional transformations for reductive cyclization, dehalogenative deuteration, and intra-and intermolecular radical addition can be achieved smoothly. Mechanistic studies indicate a single-electron photoredox catalytic system with inactivated solvent as the hydrogen atom donor.
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