4.7 Article

Carbonyl and olefin hydrosilylation mediated by an air-stable phosphorus(iii) dication under mild conditions

Journal

CHEMICAL COMMUNICATIONS
Volume 55, Issue 39, Pages 5599-5602

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc02460c

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Funding

  1. NSERC of Canada
  2. Canada Research Chair
  3. Province of Ontario for the Ontario Graduate Scholarship

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The readily-accessible, air-stable Lewis acid [(terpy) PPh][B(C6F5)(4)](2) 1 is shown to mediate the hydrosilylation of aldehydes, ketones, and olefins. The utility and mechanism of these hydrosilylations are considered.

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