Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 38, Pages 5455-5458Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc02172h
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Funding
- Japan Society of the Promotion of Science (JSPS) from the Ministry of Education, Culture, Sports, Science and Technology, Japan [JP18H02032]
- Strategic International Collaborative Research Program (SICORP)
- Adaptable and Seamless Technology Transfer Program through Target-driven R&D (A-STEP) from the Japan Science and Technology, Japan
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Crystal melting and glass formation of coordination polymers (CPs) and metal-organic frameworks (MOFs) are rare thermal events. To expand the library of melting CP/MOFs, we utilized anti-crystal engineering in ionic liquids to construct CPs. A combination of Cu+ and 4,4-bipyridin-1-ium derivatives afforded four melting CPs showing stable liquid and glassy states.
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