Journal
NEW JOURNAL OF CHEMISTRY
Volume 43, Issue 18, Pages 6830-6833Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9nj01072f
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Funding
- Ministry of Education, Culture, Sports, Science, and Technology of Japan [15H03776, 15H00930, 17K05774]
- Grants-in-Aid for Scientific Research [15H00930, 17K05774, 15H03776] Funding Source: KAKEN
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A stable primary-alkyl-substituted selenenic acid was developed as a synthetic model of selenocysteine-derived selenenic acid (Sec-SeOH) by taking advantage of a huge cavity-shaped substituent. The primary-alkyl model compound was successfully applied to model studies on the trapping reaction of protein Sec-SeOH generated in the active site of selenoenzymes with several reagents.
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