Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 36, Pages 5227-5230Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc01879d
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- University of Rome Tor Vergata'' [E81I18000220005]
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Strong C-H bond deactivation toward HAT has been observed in the reactions of the cumyloxyl radical with 1,2- and 1,3-diols, following addition of Li+ and Ca2+. Weaker effects have been observed with Mg2+. The role of the substrate structure and of the metal ion in the formation of Lewis acid-base complexes is discussed.
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