4.4 Article

Properties and reaction mechanisms of magnesium phosphate cement mixed with acetic acid

Journal

KSCE JOURNAL OF CIVIL ENGINEERING
Volume 22, Issue 1, Pages 231-235

Publisher

KOREAN SOCIETY OF CIVIL ENGINEERS-KSCE
DOI: 10.1007/s12205-017-1408-x

Keywords

acetic acid; MAPC; setting time; compressive strength; ammonia

Funding

  1. Fundamental Research Funds for the Central Universities [2015XKMS011]
  2. Open fund for JiangSu Collaborative Innovation Center for Building Energy Saving and Construct Technology [SJXTY1610]
  3. Science and Technology Program of Henan Province of China [172102210393]
  4. Fundamental Research Funds for the Central Universities
  5. JiangSu Collaborative Innovation Center for Building Energy Saving and Construct Technology
  6. Science and Technology Program of Henan Province of China

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This study aims to improve the coagulation time, strength, and construction cost of magnesium phosphate cement. We analyzed the microstructure changes in the hardened magnesium phosphate cement paste through qualitative analysis, quantitative test, microscopic examination, and research regarding adding different concentrations of acetic acid on magnesium phosphate cement slurry time, effects of flow resistance, and mechanical properties. When a moderate amount of AA was used, the setting time of MAPC mortar was significantly prolonged but was later reduced as the concentration increased. In the early phase, the degree of MAPC mortar hydration increased, whereas compressive strength significantly increased initially and increased slowly in the later phase. The crystal morphology and size of MAPC hydrates changed, and hardened MAPC became more compact in structure. The AA absorbed some ammonia in the MAPC condensation. Acetic acid can effectively regulate coagulation time, induce early hydration reaction rate, and improve the performance of magnesium phosphate cement, which can reduce the construction cost of magnesium phosphate cement.

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