Journal
CHEMICAL SOCIETY REVIEWS
Volume 48, Issue 9, Pages 2615-2656Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cs00386f
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Funding
- NSFC [21871043, 21522202, 21502017]
- Department of Science and Technology of Jilin Province [20180101185JC, 20190701012GH]
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In recent years, radical C-C bond cleavage reactions have been increasingly understood and used to perform transformations that complement traditional ionic processes. However, to date radical C-C bond cleavage/functionalization reactions have not been the subject of a dedicated review. Herein we summarize the most recent and significant developments in the radical activation and functionalization of carbon-carbon bonds, with an emphasis on both synthetic outcomes and reaction mechanisms, and highlight how these radical C-C bond cleavage reactions enable challenging transformations.
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