Journal
KOREAN JOURNAL OF CHEMICAL ENGINEERING
Volume 34, Issue 3, Pages 928-934Publisher
KOREAN INSTITUTE CHEMICAL ENGINEERS
DOI: 10.1007/s11814-016-0339-4
Keywords
Zeolitic Imidazolate Framework; ZIF-23; Cycloaddition; Propylene Oxide; CO2
Funding
- Global Frontier program [GF-HIM 2015M3A6B1065264]
- Basic Research program through the National Research Foundation of Korea [2016-03931325]
- National Research Foundation of Korea [2013M3A6B1078877] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Ask authors/readers for more resources
Zeolitic imidazolate framework ZIF-23 was prepared and used as catalyst for the solventless synthesis of cyclic carbonate from CO2 and propylene oxide with or without TBAB co-catalyst. ZIF-23 catalysts were prepared by a solvothermal or microwave method and they were characterized by various physicochemical techniques such as XRD, FT-IR, BET, TGA, and FE-SEM. The effects of reaction parameters such as temperature, reaction time, CO2 pressure, and co-catalyst on the reactivity of catalyst were investigated. ZIF-23 was recyclable up to four times without any considerable loss of its initial activity. Reaction mechanism containing the role of ZIF-23 with TBAB co-catalyst was also proposed.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available