Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 32, Pages 4723-4726Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc01037h
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Funding
- Ministry of Education, Culture, Sports, Science and Technology (MEXT) [18H04650, 17H03010, 16K13964, 16H02268]
- Mitsui Chemicals Inc
- New Energy and Industrial Technology Development Organization (NEDO)
- Mitsui Chemicals Inc and Acenet Inc. Collaborative Foundations
- Grants-in-Aid for Scientific Research [18H04650, 17H03010, 16K13964] Funding Source: KAKEN
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The chlorine dioxide radical (ClO2) was found to act as an efficient oxidizing agent for the aerobic C-H oxygenation of the side-chain methyl groups in polypropylene under photoirradiation and ambient conditions (298 K and 1 atm). The oxygenated side-chain methyl groups were selectively converted to carboxylic acid and hydroxy groups.
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