4.7 Article

MOF-templated self-polymerization of p-phenylenediamine to a polymer with a hollow box-assembled spherical structure

Journal

CHEMICAL COMMUNICATIONS
Volume 55, Issue 28, Pages 4071-4074

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc01081e

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Funding

  1. National Natural Science Foundation of China [51672021]
  2. Fundamental Research Funds for the Central Universities [ZY-1910]

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This paper presents the first transformation of MOFs to polymers without any additives by using a one-step MOF-templated self-polymerization approach. We investigate the conversion process and demonstrate that the MOF-templated self-polymerization is a new and effective approach for the in situ conversion of organic ligands to polymers and even carbon nanomaterials with maintained MOF configurations.

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