4.6 Article

Acid/base- and base/acid-switchable complexation between anionic-/cationic-pillar[6] arenes and a viologen ditosylate salt

Journal

ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 17, Issue 18, Pages 4430-4434

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ob00398c

Keywords

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Funding

  1. National Natural Science Foundation of China [21402040, 21572046]
  2. Henan Province Science and Technology Research Program [192102210197]
  3. Science and Technology Innovation Team of Henan University [18IRTSTHN005]
  4. Henan University of Engineering [D2014022]
  5. Program of 543 team of Henan University of Engineering

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Two new host-guest complexes between water-soluble anionic pillar[6] arene (WP6) or cationic pillar[6] arene (CP6) and a viologen ditosylate salt G center dot 2TsO were constructed, among which one formed from WP6 and G(2+) ions can be controlled by the sequential addition of an acid and a base (HCl and NaOH, respectively), whereas the other fabricated from CP6 and TsO- ions can be switched through the sequential addition of basic and acidic reagents (NaOH and HCl, respectively).

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