Journal
GREEN CHEMISTRY
Volume 21, Issue 11, Pages 2946-2951Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9gc00318e
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Funding
- Spanish Ministry of Economy and Competitiveness (MEC) [CTQ2016-75752-R]
- MEC within the FPI program
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Deep eutectic solvents (DESs) nowadays represent a sustainable alternative to traditional organic solvents in (bio)transformations. Herein, the use of a solvent composed of an aqueous buffer and choline chloride : glucose (1.5:1 mol/mol) is proposed, a natural DES (NADES) serving as both a cosolvent and efficient system to recycle the nicotinamide cofactor. Thus, glucose from the NADES served as a co-substrate required for several alcohol dehydrogenases to reduce different prochiral ketones, and also helped to solubilise the organic compounds to develop effective biotransformations at higher substrate concentrations.
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