Journal
ACS APPLIED NANO MATERIALS
Volume 2, Issue 5, Pages 3138-3145Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsanm.9b00462
Keywords
black phosphorus; Raman spectroscopy; density functional theory; two-dimensional heterostructure; phonon modulation
Funding
- Stewart Blusson Quantum Matter Institute (SBQMI)
- University of British Columbia
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With a new polycarbonate-film-based dry transfer method, we successfully fabricated twisted stacked black phosphorus. Optical characterization showed the overlapping area had special optical response, and high-frequency Raman spectroscopy showed unexpected blue shifts in A(g)(1) and A(g)(2) modes. Density functional theory (DFT) calculations confirmed these blue shifts in twisted bilayer black phosphorus, and revealed significant interlayer coupling effects. Charge distribution calculations indicated other interactions beyond van der Waals force may exist in twisted bilayer black phosphorus. This finding may cast some insight on phonon modulation effect and give some potential applications such as optical filters and infrared photodetectors.
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