Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 44, Pages 6213-6216Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc02989c
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Funding
- NSFC [21673301, 21473261, 21502023]
- Guangdong Natural Science Funds for Distinguished Young Scholar [2015A030306027]
- Tip-top Youth Talents of Guangdong special support program [20153100042090537]
- Fundamental Research Funds for the Central Universities
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The first example of room temperature non-noble metal homogeneous system catalyzed selective N-alkylation of anilines with alcohols by a bis-NHC manganese complex is presented. This system was applied to a large range of alcohols and anilines, including biologically relevant motifs and challenging methanol. Experimental and computational studies suggest an outer-sphere mechanism for this NHC-Mn system.
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