Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 6, Issue 11, Pages 1801-1806Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9qo00278b
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Funding
- National Natural Science Foundation of China [21625206, 21632009, 21572258, 21572259, 21421002]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000]
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The development of a thermally stable and light-insensitive nucleophilic trifluoromethoxylative reagent [Ag(bpy)(PPhtBu2)(OCF3)](2), which was synthesized in high yields via a three-step one-pot process from easily available trifluoromethyl triflate ( TFMT) and AgF at room temperature, is described. The high reactivity of reagent 2 was demonstrated by its high yielding chemoselective and stereospecific SN2-type trifluoromethoxylation with secondary alkyl nosylates.
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