Journal
PHYSICAL REVIEW B
Volume 99, Issue 17, Pages -Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevB.99.174442
Keywords
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Funding
- U.K. Engineering and Physical Sciences Research Council [EP/N034872/1, EP/N034694/1]
- National Natural Science Foundation of China [11774399]
- Chinese Academy of Sciences [QYZDB-SSW-SLH043]
- Beijing Natural Science Foundation [Z180008]
- Shanghai Pujiang Program [17PJ1406200]
- Lincoln College, Oxford
- EPSRC [EP/N034694/1, EP/N027671/1, EP/N034872/1] Funding Source: UKRI
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We present AC and DC magnetometry, heat capacity, muon spin relaxation (mu SR), and resonant inelastic x-ray scattering (RIXS) studies of the pyrochlore osmate Y2Os2O7. Consistent with previous results, we observe a small Curie-Weiss effective moment of approximately 0.4 mu(B) and spin freezing at a temperature T-f similar or equal to 5 K. On the other hand, our analysis of the RIXS spectra with single-ion energy-level calculations implies a nonmagnetic J(eff) = 0 ground state on the Os4+ sites, with the spin-orbit interaction, Hund's coupling, and trigonal distortion of OsO6 octahedra, all important in modeling the observed spectra. From high-field magnetization data, we show that the paramagnetic moment is most likely due to large moments mu(eff) similar or equal to 3 mu(B) on only a small fraction f similar or equal to 0.02 of Os sites. We suggest disorder-related effects, such as oxygen nonstoichiometry or site interchange between Os and Y ions, as the most likely explanation for the magnetic response of this material.
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