Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 46, Pages 6503-6506Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc02738f
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- JSPS KAKENHI [JP17K05864]
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Copper-catalyzed arylstannylation of arynes has been developed. This transformation enables variously substituted ortho-stannylbiaryls and teraryls to be constructed straightforwardly. An electron-deficient tin center is the key, and thus the single or dual insertion of arynes into arylstannanes is precisely controllable by simply changing the equivalence of aryne precursors.
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