Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 46, Pages 6583-6586Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc03281a
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Funding
- Ministry of Science and Technology of China [2016YFA0203400, 2017YFA0206600]
- National Natural Science Foundation of China [51673050, 91856115, 51673080]
- Chinese Academy of Sciences
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Stable luminescent pi-radicals with doublet emission have attracted growing attention for functional molecular materials. However, their chiroptical properties, particularly their doublet emission-based circularly polarized luminescence, have never been investigated. Here, we investigate the circularly polarized luminescence (CPL) properties of a series of achiral luminescent open-shell pi-radicals through various chirality regulation approaches, including induction by a magnetic field, supramolecular coassembly and chiral liquid crystal encapsulation.
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