4.5 Article

Ultradeep electron cyclotron resonance plasma etching of GaN

Journal

JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A
Volume 35, Issue 6, Pages -

Publisher

A V S AMER INST PHYSICS
DOI: 10.1116/1.4994829

Keywords

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Funding

  1. U.S. Department of Energy (DOE), the Office of Energy Efficiency and Renewable Energy (EERE), the Advanced Manufacturing Office (AMO)
  2. U.S. Department of Energy by Lawrence Livermore National Laboratory [DE-AC52-07NA27344, LLNL-JRNL-730843]

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Ultradeep (>= 5 mu m) electron cyclotron resonance plasma etching of GaN micropillars was investigated. Parametric studies on the influence of the applied radio-frequency power, chlorine content in a Cl-2/Ar etch plasma, and operating pressure on the etch depth, GaN-to-SiO2 selectivity, and surface morphology were performed. Etch depths of >10 mu m were achieved over a wide range of parameters. Etch rates and sidewall roughness were found to be most sensitive to variations in RF power and % Cl-2 in the etch plasma. Selectivities of >20:1 GaN:SiO2 were achieved under several chemically driven etch conditions where a maximum selectivity of similar to 39:1 was obtained using a 100% Cl-2 plasma. The etch profile and (0001) surface morphology were significantly influenced by operating pressure and the chlorine content in the plasma. Optimized etch conditions yielded >10 mu m tall micropillars with nanometer-scale sidewall roughness, high GaN:SiO2 selectivity, and nearly vertical etch profiles. These results provide a promising route for the fabrication of ultradeep GaN microstructures for use in electronic and optoelectronic device applications. In addition, dry etch induced preferential crystallographic etching in GaN microstructures is also demonstrated, which may be of great interest for applications requiring access to non-or semipolar GaN surfaces. (C) 2017 American Vacuum Society.

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