Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 49, Pages 7025-7028Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc02421b
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Funding
- EPSRC [EP/K039547/1]
- University of Manchester
- Ramsay Memorial Trust
- EPSRC [EP/K039547/1] Funding Source: UKRI
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We report an empirical correlation between the blocking temperature of large energy barrier SMMs and the relaxation time at the point where the Raman and Orbach relaxation mechanisms have the same rate; this supports the idea that the ability to retain magnetisation is controlled by the Raman relaxation process in these materials.
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