Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 47, Pages 6783-6786Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc03079d
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Funding
- National Science Foundation of China [21873102]
- Strategic Priority Research Program of the Chinese Academy of Science [XDB20000000]
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Redox reactions of K5Bi4 and CpCo(CO)(2)/Rh(CO)(2)(acac) (acac = acetylacetonate) in ethylenediamine (en) yielded the first Bi-7(3-) adducts [Bi7M3(CO)(3)](2-) (M = Co, 1a; Rh, 2a) that have a new architype 10-vertex deltahedral structure, resulting from the unprecedented polycyclic eta(5)-coordination addition reaction of the Bi-7(3-) cage and three MCO+ fragments.
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