Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 47, Pages 6743-6746Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc02380a
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Funding
- Japan Society for the Promotion of Science (JSPS) [26220911, 16K14478]
- MEXT, Japan
- JSPS [16J08114]
- Grants-in-Aid for Scientific Research [16K14478, 16J08114] Funding Source: KAKEN
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A hydrophobic MOF, OPA/MIL-125-NH2, whose Ti cluster was alkylated with octadecylphosphonic acid (OPA), was found to enhance photocatalytic H2O2 production in a two-phase system. Its activity exceeded that of linker-alkylated MIL-125-NH2. OPA/MIL-125-NH2 was modified on its outermost surface, which resulted in the activity enhancement while preserving the inner pores of the inherent MOF.
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