4.7 Article

Selective and quantitative synthesis of a linear [3]catenane by two component coordination-driven self-assembly

Journal

CHEMICAL COMMUNICATIONS
Volume 55, Issue 48, Pages 6866-6869

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc03336j

Keywords

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Funding

  1. NRF - Ministry of Science and ICT (MSIT) [NRF-2016R1A2B4007433, NRF-2018R1D1A1B07049304]
  2. Center for Advanced Meta-Materials - MSIT [2019M3A6B3030636]
  3. Korea Basic Science Institute under the RD program [D39701]
  4. National Research Council of Science & Technology (NST), Republic of Korea [D39701] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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Here we report the synthesis of a linear [3] catenane comprised of three interlocking rings, by coordination-driven self-assembly. Naphthalene-based acceptor A1 and triazole-based donor L1 were utilized for the self-assembly reaction, which facilitated the formation of linear [3] catenane topology through synergistic non-covalent intercycler interactions (pi-pi, CH-pi and CH-N).

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