4.7 Article

Anion exchange of a cationic Cd(ii)-based metal-organic framework with potassium ferricyanide towards highly active Fe3C-containing Fe/N/C catalysts for oxygen reduction

Journal

CHEMICAL COMMUNICATIONS
Volume 55, Issue 48, Pages 6930-6933

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc02390a

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Funding

  1. National Key Research Program [2017YFA0206500]
  2. National Natural Science Foundation of China [21533005, 216673275, 21573107, 21401099]
  3. Fundamental Research Funds for the Central Universities [3207047406]

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' A highly active and stable Fe3C-containing Fe/N/C catalyst, derived from a cationic Cd(II)-based metal-organic framework involving accurate control over Fe-doping via anion-exchange with potassium ferricyanide, shows superior oxygen reduction performance over the benchmark Pt/C catalyst in an alkaline electrolyte.

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