Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 50, Pages 7187-7190Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc02882j
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Funding
- National Natural Science Foundation of China [21502130]
- 1000-Youth Talents Program
- Fundamental Research Funds for the Central Universities
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We constructed a library of diarylsydnone (DASyd) candidates in search of a photoclickable reaction toward alkynes, enabling an ultra-accelerated reactivity, while suppressing the background cycloaddition in the dark. The in vitro and in vivo protein labelling experiments revealed that the photo-accelerated DASyd-alkyne cycloaddition exhibits robust selectivity.
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