Tailored properties of hematite particles with different size and shape

Red cubic and spherical hematite red cool pigments of different particle size were synthesized following two different methods. Cubic and spherical particles with larger particle sizes were obtained through a gel sot method using chloride and nitrilotriacetate ions as shape controllers, and changing the starting temperature to control the final particles size. Smaller spherical particles were synthesized more rapidly following a catalytic phase transformation method in which the size control is obtained by varying the reagent concentration. Cool properties for the obtained particles were evaluated by calculating the solar reflectance for all hematite samples. The cool properties differ depending on the particle size and shape. By controlling the final size and morphology of pigment particles it is possible to obtain pigments with the desired cool properties. Pigment color properties were also evaluated using CIE XYZ and CIE xyY color spaces. (C) 2015 Elsevier Ltd. All rights reserved.