Journal
DYES AND PIGMENTS
Volume 114, Issue -, Pages 283-289Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2014.11.022
Keywords
Perylene diimide; Thienylenevinylene; Organic solar cell; Solution process; Nonfullerene acceptor; Fullerene-free
Funding
- 973 Program [2011CB808401]
- NSFC [91433114, 21025418, 51261130582]
- Chinese Academy of Sciences
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A small molecule and a polymer based on perylene diimide and thienylenevinylene were designed and synthesized. Both small molecule and polymer exhibited excellent thermal stability with decomposition temperatures of >400 degrees C and strong absorption in the visible region (300-800 nm). These two compounds showed highest occupied molecular orbital levels of -5.57 and -5.70 eV and lowest unoccupied molecular orbital levels of -3.72 and -3.67 eV, respectively. Solution processed fullerene-free polymer solar cells based on the small molecule acceptor and the polymer acceptor afforded power conversion efficiencies of up to 0.69% and 1.00%, respectively. Comparative studies of the absorption, energy levels, charge transport, morphology and photovoltaic properties of the small molecule and polymer were carried out. (C) 2014 Elsevier Ltd. All rights reserved.
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