4.7 Article

A new naphthalimide derivative as a selective fluorescent and colorimetric sensor for fluoride, cyanide and CO2

Journal

DYES AND PIGMENTS
Volume 120, Issue -, Pages 288-292

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2015.04.029

Keywords

Carbon dioxide sensor; Fluoride ion sensor; Cyanide ion sensor; Fluorescent sensor; Colorimetric sensor; Anion recognition

Funding

  1. National Research Foundation of Korea (NRF) grant - Korea government (MEST) (CRI) [2012R1A3A2048814]
  2. National Natural Science Foundation of China [21276251, 21422606]

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A new naphthalimide derivative 1 is reported as an anion-activated CO2 chemosensor. Among the various anions, chemosensor 1 displayed selective colorimetric and fluorescence changes with F- and DN-. Hydrogen bonding interactions between amine groups and anions can be attributed to these changes. The exposure of CO2 revived the original color and fluorescence, so that distinct On-Off-On fluorescence emission changes were observed, for this anion-activated CO2 sensing mechanism. (C) 2015 Elsevier Ltd. All rights reserved.

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