Journal
CHEMICAL COMMUNICATIONS
Volume 55, Issue 50, Pages 7215-7218Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc02648g
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Funding
- National Key R&D Program of China [2016YFB0401004]
- National Natural Science Foundation of China [91833304, 51625301, 51573059]
- 973 Project [2015CB655003]
- Guangdong Provincial Department of Science and Technology [2016B090906003, 2016TX03C175]
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The effect of boronic ester substitution on the room-temperature phosphorescence properties of phenoxathiine-based derivatives was thoroughly investigated. A significantly improved phosphorescence quantum efficiency of up to 20% in the crystalline state was achieved by delicate molecular manipulation for both enhanced spin-orbital coupling and compact intermolecular packing.
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